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There is a list of tutorials suitable for experienced programmers on the BeginnersGuide/Tutorials page. There is also a list of resources in other languages which might be useful if English is not your first language.
The online documentation is your first port of call for definitive information. There is a fairly brief tutorial that gives you basic information about the language and gets you started. You can follow this by looking at the library reference for a full description of Python's many libraries and the language reference for a complete (though somewhat dry) explanation of Python's syntax. If you are looking for common Python recipes and patterns, you can browse the ActiveState Python Cookbook
